The content presented here represents the most current version of this section, which was printed in the 24th edition of Standard Methods for the Examination of Water and Wastewater.
Abstract:

Salinity is an important unitless property of industrial and natural waters. It was originally conceived as a measure of the mass of dissolved salts in a given mass of solution. The experimental determination of the salt content by drying and weighing presents some difficulties due to the loss of some components. The only reliable way to determine the true or absolute salinity of a natural water is to make a complete chemical analysis. However, this method is time consuming and cannot yield the precision necessary for accurate work. Thus, to determine salinity, one normally uses indirect methods involving the measurement of a physical property such as conductivity, density, sound speed, or refractive index. From an empirical relationship of salinity and the physical property detemined for a standard solution, it is possible to calculate salinity. The resultant salinity is no more accurate than the empirical relationship. The precision of the measurement of a physical property determines the precision in salinity. Following are the precisions of various physical measurements and the resultant salinity presently attainable with commercial instruments:

Although conductivity has the greatest precision, it responds only to ionic solutes. Density, although less precise, responds to all dissolved solutes.

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CITATION

Standard Methods Committee of the American Public Health Association, American Water Works Association, and Water Environment Federation. 2520 salinity In: Standard Methods For the Examination of Water and Wastewater. Lipps WC, Baxter TE, Braun-Howland E, editors. Washington DC: APHA Press.

DOI: 10.2105/SMWW.2882.028

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